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Natural Gas (NG) is an alternative fuel which has attracted a lot of attention recently, in particular in the US due to shale gas availability. The higher hydrogen-to-carbon (H/C) ratio, compared to gasoline, allows for decreasing carbon dioxide emissions throughout the entire engine map. Furthermore, the high knock resistance of NG allows increasing the efficiency at high engine loads compared to fuels with lower knock resistance. NG direct injection (DI) allows for fuel to be added after intake valve closing (IVC) resulting in an increase in power density compared to an injection before IVC. Steady-state engine tests were performed on a single-cylinder research engine equipped with gasoline (E10) port-fuel injection (PFI) and NG DI to allow for in-cylinder blending of both fuels. Knock investigations were performed at two discrete compression ratios (CR), 10.5 and 12.5.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Their easy availability, lower well-to-wheel emissions, and relative ease of use with existing engine technologies have made ethanol and ethanol-gasoline blends a viable alternative to gasoline for use in spark-ignition (SI) engines. The lower energy density of ethanol and ethanol-gasoline blends, however, results in higher volumetric fuel consumption compared with gasoline. Also, the higher latent heat of vaporization can result in cold-start issues with higher-level ethanol blends. On the other hand, a higher octane number, which indicates resistance to knock and potentially enables more optimal combustion phasing, results in better engine efficiency, especially at higher loads. This paper compares the fuel consumption and emissions of two ethanol blends (E50 and E85) with those for gasoline when used in conventional (non-hybrid) and power-split-type plug-in hybrid electric vehicles (PHEVs).

Homogeneous charge compression ignition (HCCI) has received much attention in recent years due to its ability to reduce both fuel consumption and NO emissions compared to normal spark-ignited (SI) combustion. However, due to the limited operating range of HCCI, production feasible engines will need to employ a combination of combustion strategies, such as stoichiometric SI combustion at high loads and leaner burn spark-assisted compression ignition (SACI) and HCCI at intermediate and low loads. The goal of this study was to extend the high load limit of HCCI into the SACI region while maintaining a stoichiometric equivalence ratio. Experiments were conducted on a single-cylinder research engine with fully flexible valve actuation. In-cylinder pressure rise rates and combustion stability were controlled using cooled external EGR, spark assist, and negative valve overlap. Several engine loads within the SACI regime were investigated.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

The use of exhaust gas recirculation (EGR) in internal combustion engines has significant impacts on combustion and emissions. EGR can be used to reduce in-cylinder NOx production, reduce emitted particulate matter, and enable advanced forms of combustion. To maximize the benefits of EGR, the exhaust gases are often cooled with on-engine liquid to gas heat exchangers. A common problem with this approach is the build-up of a fouling layer inside the heat exchanger due to thermophoresis and condensation, reducing the effectiveness of the heat exchanger in lowering gas temperatures. Literature has shown the effectiveness to initially drop rapidly and then approach steady state after a variable amount of time. The asymptotic behavior of the effectiveness has not been well explained. A range of theories have been proposed including fouling layer removal, changing fouling layer properties, and cessation of thermophoresis.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

A program to explore the effects of natural and additive-derived cetane on various aspects of diesel performance and combustion has been carried out. Procedures have been developed to measure diesel engine fuel consumption and power to a high degree of precision. These methods have been used to measure fuel consumption and power in three heavy-duty direct-injection diesel engines. The fuel matrix consisted of three commercial fuels of cetane number (CN) of 40-42, the same fuels raised to CN 48-50 with a cetane improver additive, and three commercial fuels of base CN 47-50. The engines came from three different U.S. manufacturers and were of three different model years and emissions configurations. Both fuel economy and power were found to be significantly higher for the cetane-improved fuels than for the naturally high cetane fuels. These performance advantages derive mainly from the higher volumetric heat content inherent to the cetane-improved fuels.

Present-day implementations of premixed compression ignition low temperature (PCI) combustion in diesel engines use higher levels of exhaust gas recirculation (EGR) than conventional diesel combustion. Two common devices that can be used to achieve high levels of EGR are an intake throttle and a variable geometry turbocharger (VGT). Because the two techniques affect the engine air system in different ways, local combustion conditions differ between the two in spite of, in some cases, having similar burn patterns in the form of heat release. The following study has developed from this and other observations; observations which necessitate a deeper understanding of emissions formation within the PCI combustion regime. This paper explains, through the use of fundamental phenomenological observations, differences in ignition delay and emission indices of particulate matter (EI-PM) and nitric oxides (EI-NOx) from PCI combustion attained via the two different techniques to flow EGR.

This study investigates the impact of transient engine operation on the emissions formed during a tip-in procedure. A medium-duty production V-8 diesel engine is used to conduct experiments in which the rate of pedal position change is varied. Highly-dynamic emissions instrumentation is implemented to provide real-time measurement of NOx and particulate. Engine subsystems are analyzed to understand their role in emissions formation. As the rate of pedal position change increases, the emissions of NOx and particulates are affected dramatically. An instantaneous load increase was found to produce peak NOx values 1.8 times higher and peak particulate concentrations an order of magnitude above levels corresponding to a five-second ramp-up. The results provide insight into relationship between driver aggressiveness and diesel emissions applicable to development of drive-by-wire systems. In addition, they provide direct guidance for devising low-emission strategies for hybrid vehicles.

This paper describes the concept and a practical implementation of piston-compounding. First, a detailed computer simulation of the piston-compounded engine is used to shed light into the thermodynamic events associated with the operation of this engine, and to predict the performance and fuel economy of the entire system. Starting from a baseline design, the simulation is used to investigate changes in system performance as critical parameters are varied. The latter include auxiliary cylinder and interconnecting manifold volumes for a given main cylinder volume, auxiliary cylinder valve timings in relation to main cylinder timings, and degree of heat loss to the coolant. Optimum designs for either highest power density or highest thermal efficiency (54%) are thus recommended. It is concluded that a piston-compounded adiabatic engine concept is a promising future powerplant.

Instantaneous piston surface temperatures and heat flux rates were measured inside and outside the end-gas zone of a single-cylinder research engine operated under light and heavy knocking conditions. The engine was run with center and rear side spark-plug configurations, thus alternating the position of the heat flux probes relative to the end gas. Heat transfer data were collected over 88 engine cycles for each of which knock intensity was determined by heat release analysis. Under light knock, the ensemble-averaged peak heat-flux at locations near the end-gas increased with spark advance towards heavier knock, showing significant departure from its trend prior to the onset of knock. Under heavy knock, the ensemble-averaged peak heat-flux increased throughout the piston crown. Despite showing significant scatter, individual cycle, peak heat-flux values near the end-gas region were found to follow an increasing trend with knock intensity under light knocking conditions.

A comprehensive quasi-dimensional computer simulation of the spark-ignition (SI) engine was used to explore part-load, fuel economy benefits of the Variable Stroke Engine (VSE) compared to the conventional throttled engine. First it was shown that varying stroke can replace conventional throttling to control engine load, without changing the engine characteristics. Subsequently, the effects of varying stroke on turbulence, burn rate, heat transfer, and pumping and friction losses were revealed. Finally these relationships were used to explain the behavior of the VSE as stroke is reduced. Under part load operation, it was shown that the VSE concept can improve brake specific fuel consumption by 18% to 21% for speeds ranging from 1500 to 3000 rpm. Further, at part load, NOx was reduced by up to 33%. Overall, this study provides insight into changes in processes within and outside the combustion chamber that cause the benefits and limitations of the VSE concept.

The effect of natural gas composition on ignition delay has been investigated numerically by using detailed and reduced chemical kinetic mechanisms. Three different blends of natural gas have been analyzed at pressures and temperatures that are typical of top dead center conditions in compression ignition engines. The predicted ignition delay shows a decrease with temperature in an Arrhenius manner and has a first order dependence on pressure. Similar trends have been observed by Naber et al. [1] in their experimental study of natural gas autoignition in a bomb. It is shown that two kinetic mechanisms (GRI-Mech 1.2 and reduced set DRM22) are best capable of predicting the ignition delay of natural gas under compression ignition conditions. The DRM22 mechanism has been chosen for further studies as t involves lower computational costs compared to the full GRI-Mech 1.2 mechanism.

An early-design methodology for predicting both expected fuel economy and catalyst-out CO, HC and NOx concentrations during arbitrarily-defined transient cycles is presented. The methodology is based on utilizing a vehicle-powertrain model with embedded maps of fully warmed up engine-out performance and emissions, and appropriate temperature-dependent correction factors to account for not fully warmed up conditions during transients. Similarly, engine-out emissions are converted to catalyst-out emissions using conversion efficiencies based on the catalyst brick temperature. A crucial element of the methodology is hence the ability to predict heat flows and component temperatures in the engine and the exhaust system during transients, consistent with the data available during concept definition and early design phases.

Piston heat transfer measurements were taken under varying knock intensity in a modern spark-ignition engine combustion chamber. For a range of knocking spark timings, two knock intensity levels were obtained by using a high (80°C) and a low (50°C) cylinder head coolant temperature. Data were taken with a central and a side spark plug configuration. When the spark-plug was placed at the center of the combustion chamber, a linear variation of peak heat flux with knock intensity was found in the end-gas region. Very large changes in peak heat flux (on the order of 100%) occurred at probes whose relative location with respect to the end gas zone changed from being within (80°C coolant case) to being outside the zone (50°C coolant case). With side spark-plug, distinct differences in peak heat flux occurred at all probes and under all knock intensities, but the correlation between knock intensity and heat flux was not linear.